The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.
The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.
Lanthanoids primarily show three oxidation states (+2, +3, +4). Among these oxidation states, +3 state is the most common. Lanthanoids display a limited number of oxidation states because the energy difference between 4f, 5d, and 6s orbitals is quite large. On the other hand, the energy difference between 5f, 6d, and 7s orbitals is very less. Hence, actinoids display a large number of oxidation states. For example, uranium and plutonium display +3, +4, +5, and +6 oxidation states while neptunium displays +3, +4, +5, and +7. The most common oxidation state in case of actinoids is also +3.
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Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following points:
2 years ago
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What can be inferred from the magnetic moment values of the following complex species? Example Magnetic Moment (BM)
2 years ago
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Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.
2 years ago
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Write the electronic configurations of the elements with the atomic numbers 61, 91, 101, and 109.
2 years ago
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Compare the chemistry of the actinoids with that of lanthanoids with reference to: (i) electronic configuration (ii) oxidation states and (iii) chemical reactivity.
2 years ago
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