The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molal solution of a nonvolatile solute in it.
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03/01/2022 5:16 pm
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The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molal solution of a nonvolatile solute in it.
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03/01/2022 5:28 pm
1 molal solution means 1 mol of the solute is present in 1000 g of the solvent (water).
Molar mass of water = 18 g mol-1
∴ Number of moles present in 1000 g of water = \(\frac{1000}{18}\)
= 55.56 mol
Therefore, mole fraction of the solute in the solution is x2 = \(\frac{1}{1+55.56}\) = 0.0177
It is given that,
Vapour pressure of water, p10 = 12.3 kPa
Applying the relation, \(\frac{p_1^0 - p_1}{p_1^0} = x_2\)
⇒ \(\frac{12.3 - p_1}{12.3}\) = 0.0177
⇒ 12.3 - p1 = 0.2177
⇒ p1 = 12.0823
= 12.08 kPa (approximately)
Hence, the vapour pressure of the solution is 12.08 kPa.
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