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An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200 g of water. Calculate the molality of the solution.

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An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200 g of water. Calculate the molality of the solution. If the density of the solution is 1.072 g mL-1, then what shall be the molarity of the solution?

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Molar mass of ethylene glycol [C2H4OH)2]

= 2 × 12 + 6 × 1 + 2 ×16

= 62 g mol-1

Number of moles of ethylene glycol = \(\frac{222.6g}{62\;gmol^{-1}}\)

= 3.59 mol

Therefore, molality of the solution = \(\frac{3.59\;mol}{0.200\;kg}\)

= 17.95 m

Total mass of the solution = (222.6 + 200) g

= 422.6 g

Given,

Density of the solution = 1.072 g mL-1

∴ Volume of the solution = \(\frac{422.6\;g}{1.072\;g\;mL^{-1}}\)

= 394.22 mL

= 0.3942 × 10-3 L

Molarity of the solution = \(\frac{3.59\;mol}{0.39422 \times 10^{-3}L}\)

= 9.11 M

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