The rate of the chemical reaction doubles for an increase of 10 K in absolute temperature from 298 K. Calculate Ea.
The rate of the chemical reaction doubles for an increase of 10 K in absolute temperature from 298 K. Calculate Ea.
It is given that T1 = 298 K
∴ T1 = (298 + 10)K = 308 K
We also know that the rate of the reaction doubles when temperature is increased by 10°.
Therefore, let us take the value of k1 = k and that of k2 = 2k
Also, R = 8.314 J K-1 mol-1
Now, substituting these values in the equation:
log \(\frac{k_2}{k_1}\) = \(\frac{E_a}{2.303 R}\)\(\Big[\frac{T_2 -T_1}{T_1T2}\Big]\)
We get,
\(\frac{2k}{k}\) = \(\frac{E_a}{2.303 \times 8.314}\)\(\Big[\frac{10}{298 \times 308}\Big]\)
⇒ log 2 = \(\frac{E_a}{2.303 \times 8.314}\)\(\Big[\frac{10}{298 \times 308}\Big]\)
⇒ Ea = \(\frac{2.303 \times 8.314 \times 298 \times 308 \times log 2}{10}\)
= 52897.78 J mol-1
= 52.9 kJ mol-1
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