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One mole of CH3COOH and one mole of C2H5OH reacts to produce 2/3 mole of CH3COOC2H5. The equilibrium constant is :

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One mole of CH3COOH and one mole of C2H5OH reacts to produce 2/3 mole of CH3COOC2H5. The equilibrium constant is :

(a) 2

(b) +2

(c) -4

(d) +4

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(d) +4

Explanation:

CH3COOH + C2H5OH → CH3COOC2H5 + H2O

At start   1 mole   1 mole   0     0

At equb.   1- 2/3   1- 2/3    2/3   2/3

Let the total volume = V L

∴ [CH3COOH] = 1/3V mol/L

[C2H5OH] = 1/3 V mol/L

[CH3COOC2H5] = 2/3 V mol/L

[H2O] = 2/3 V mol/L

∴  K = (2/3 V x 2/3 V)/(1/3V x 1/3 V) = 4

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