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Some inert gas is added at constant volume to the following reaction at equilibrium NH4HS(s) ⇌ NH3(g) + H2S(g) Predict the effect of adding the inert gas:

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Some inert gas is added at constant volume to the following reaction at equilibrium

NH4HS(s) ⇌ NH3(g) + H2S(g)

Predict the effect of adding the inert gas:

(a) The equilibrium shifts in the forward direction

(b) The equilibrium shifts in the backward direction

(c) The equilibrium remains unaffected

(d) The value of  Kp is increased

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Correct answer: (c) The equilibrium remains unaffected

Explanation:

Addition of inert gas at constant volume has no effect on equilibrium.

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