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If pKb for fluoride ion at 25°C is 10.83, the ionisation constant of hydrofluoric acid in water at this temperature is

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If pKb for fluoride ion at 25°C is 10.83, the ionisation constant of hydrofluoric acid in water at this temperature is

(a) 3.52 × 10-3

(b) 6.75 × 10-4

(c) 5.38 × 10-2

(d) 1.74 × 10-5

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Correct answer: (b) 6.75 × 10-4

Explanation:

Kw = Ka x Kb

Kb = 10-10.83 = 1.48 × 10-11

∴ Ka = \(\frac{K_w}{K_b}\)

= \(\frac{10^{-14}}{1.48 \times 10^{-11}}\)

= 6.75 × 10-4

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