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For the reaction : 2BaO2(s) ⇌ 2BaO(s) + O2(g); ΔH = +ve. In equilibrium condition, pressure of O2 is dependent on

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For the reaction :

2BaO2(s) ⇌ 2BaO(s) + O2(g); ΔH = +ve.

In equilibrium condition, pressure of O2 is dependent on

(a) mass of BaO2

(b) mass of BaO

(c) temperature of equilibrium

(d) mass of BaO2 and BaO both

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Correct answer: (c) temperature of equilibrium

Explanation:

For the reaction

2BaO2(s) ⇌ 2BaO(s) + O2(g); ΔH = +ve.

At equilibrium KP = PO2

Hence, the value of equilibrium constant depends only upon partial pressure of O2. Further on increasing temperature formation of O2 increases as this is an endothermic reaction. Hence, pressure of O2 is dependent on temperature.

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