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Which of the following is arranged in the increasing order of enthalpy of vaporisation?
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06/10/2020 11:44 am
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Which of the following is arranged in the increasing order of enthalpy of vaporisation?
(a) NH3, PH3, AsH3
(b) AsH3, PH3, NH3
(c) NH3, AsH3, PH3
(d) PH3, AsH3, NH3
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06/10/2020 11:48 am

(d) PH3, AsH3, NH3
Explanation:
The order of heat of vaporisation or boiling point of the hydrides of VA group depend upon their molecular weight. Anomalous behaviour of NH3 is due to H-bonding present in NH3. Thus the correct order is
NH3 > AsH3 > PH3
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