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S + O2 → SO2 + x kcal .....(1) SO2 + 1/2O2 → SO3 + y kcal ....(2) The heat of formation of SO3 in the above reaction is

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S + O2 → SO2 + x kcal     .....(1)

SO2 + 1/2O2 → SO3 + y kcal  ....(2)

The heat of formation of SO3 in the above reaction is

(a) (x + y)

(b) (x – y)

(c) (2x – y)

(d) (2x + y)

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(a) (x + y)

Explanation:

S + O2 → SO2 + x      .....(1)

SO2 + 1/2O2 → SO3 + y   ....(2)

Adding (i) and (ii), we have

S + O2 + SO2 + 1/2O2 → SO2 + SO3

S + 1 1/2O2 → SO3

So, heat of formation of SO3 will be (x + y).

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