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Enthalpy of neutralisation of CH3COOH by NaOH is –50.6 kJ/mol and the heat of neutralisation of a strong acid with NaOH is –55.9 kJ/mol.

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Enthalpy of neutralisation of CH3COOH by NaOH is –50.6 kJ/mol and the heat of neutralisation of a strong acid with NaOH is –55.9 kJ/mol. The value of ΔH for the ionisation of CH3COOH is :

(a) 3.5 kJ/mol

(b) 4.6 kJ/mol

(c) 5.3 kJ/mol

(d) 6.4 kJ/mol

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(c) 5.3 kJ/mol

Explanation:

Enthalpy of neutralisation of CH3COOH by NaOH is -50.6 kJ/mole ; for strong acid and base this value is 55.9 kJ/mole. Heat evolved in the first case is less as some heat is used up in ionisation of CH3COOH. So, ΔH for ionisation of CH3COOH = 55.9 – 50.6 = 5.3 kJ/mol.

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