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Choose the reaction in which ΔH is not equal to ΔU?

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Choose the reaction in which ΔH is not equal to ΔU?

(a) C(graphite) + O2(g) → CO2(g)

(b) C2H4(g) + H2(g) → C2H6(g)

(c) 2C(graphite) + H2(g) → C2H2(g)

(d) H2(g) + I2(g) → 2HI(g)

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(b) C2H4(g) + H2(g) → C2H6(g)

Explanation:

ΔH is given by

ΔH = ΔU + ΔngRT

When Δng = 0, ΔH = ΔU

When Δng ≠ 0, ΔH ≠ ΔU

For C2H4(g) + H2(g) → C2H6(g)

Δng = 1 - 2 = -1

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