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The (S°) of the following substances are: CH4 (g) 186.2 JK^–1 mol^–1 O2 (g) 205.2 JK^–1 mol^–1 CO2(g) 213.6 JK^–1 mol^–1 H2O(g) 69.9.JK^–1 mol^–1 The entropy change (ΔS°) for the reaction

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The (S°) of the following substances are:

CH4 (g) 186.2 JK–1 mol–1

O2 (g) 205.2 JK–1 mol–1

CO2(g) 213.6 JK–1 mol–1

H2O(g) 69.9.JK–1 mol–1

The entropy change (ΔS°) for the reaction

CH4(g) + 2O2(g) → CO2(g) + 2H2O(l) is:

(a) -312.5 J K–1 mol–1

(b) -242.8 J K–1 mol–1

(c) -108.1 J K–1 mol–1

(d) -37.6 J K–1 mol–1

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Correct answer: (b) -242.8 J K–1 mol–1

Explanation:

ΔS° = S°CO2 + 2 x S°H2O - (S°CH4 + 2 x S°O2)

= (213.6 + 2 × 69.9) – (186.2 + 2 × 205.2)

= -242.8 J K–1 mol–1

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