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The enthalpies of formation of Al2O3 and Cr2O3 are -1596 kJ and -1134 kJ respectively. ΔH for the reaction 2Al + Cr2O3 → 3Cr + Al2O3 is

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The enthalpies of formation of Al2O3 and Cr2O3 are -1596 kJ and -1134 kJ respectively. ΔH for the reaction 2Al + Cr2O3 → 3Cr + Al2O3 is

(a) -2730 kJ

(b) -462 kJ

(c) -1365 kJ

(d) +2730 kJ

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Correct answer: (b) -462 kJ

Explanation:

2Al + 3/2O2 → Al2O3, ΔH = -1596 kJ   .....(i)

2Cr + 3/2O2 → Cr2O3, ΔH = -1134 kJ   .....(ii)

By (i) – (ii)

2Al + Cr2O3 → 2Cr + Al2O3, ΔH = -462 kJ

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