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If bond enthalpies of N ≡ N, H –H and N –H bonds are x1, x2 and x3 respectively, ΔHf^o for NH3 will be

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If bond enthalpies of N ≡ N, H –H and N –H bonds are x1, x2 and x3 respectively, ΔHfo for NH3 will be

(a) x1 + 3x2 – 6x3

(b) 1/2x1 + 3/2x2 – 3x3

(c) 3x3 – 1/2x1 – 3/2x2

(d) 6x3 – x1 – 3x2

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Correct answer: (b) 1/2x1 + 3/2x2 – 3x3

Explanation:

\(\frac{1}{2}\) N2 + \(\frac{3}{2}\)H2 → NH3

\(\frac{1}{2}\)x1 + \(\frac{3}{2}\)x2 – 3x3

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