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For which one of the processes represented by the following equations the enthalpy (heat) change is likely to be negative

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For which one of the processes represented by the following equations the enthalpy (heat) change is likely to be negative

(a) Cl-(g) + aq → Cl-(aq)

(b) Cl(g) → Cl+(g) + e-

(c) 1/2Cl2(g) → Cl(g)

(d) Cl2(l) → Cl2(g)

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Correct answer: (a) Cl-(g) + aq → Cl-(aq)

Explanation:

Gaseous ions, when dissolved in water, get hydrated and heat is evolved (heat of hydration).

Cl-(g) + aq → Cl-(aq) is such reaction.

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