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For the reaction taking place at certain temperature NH2COONH4(s) ⇌ 2NH3(g) + CO2(g), if equilibrium pressure is 3X bar then ΔrG° would be

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For the reaction taking place at certain temperature

NH2COONH4(s) ⇌ 2NH3(g) + CO2(g),

if equilibrium pressure is 3X bar then ΔrG° would be

(a) -RT ln 9 – 3RT ln X

(b) RT ln 4 – 3RT ln X

(c) -3RT ln X

(d) None of these

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Correct answer: (d) None of these

Explanation:

ΔG° = -RT ln KP; KP = (2x)2 X = 4x3

ΔG° = -RT ln (4X3)

ΔG° = -RT ln 4 – 3RT ln X

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