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Following reaction occurs in an automobile 2C8H18(g) + 25O2(g) → 16CO2(g) + 18H2O(g). The sign of ΔH, ΔS and ΔG would be

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Following reaction occurs in an automobile 2C8H18(g) + 25O2(g) → 16CO2(g) + 18H2O(g). The sign of ΔH, ΔS and ΔG would be

(a) +, –, +

(b) –, +, – 

(c) –, +, +

(d) +, +, –

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Correct answer: (b) –, +, – 

Explanation:

For combustion reaction, ΔH is negative,

Δn = (16 + 18) - (25 + 2) = +7

so ΔS is +ve, reaction is spontaneous, hence ΔG is –ve.

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