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A reaction is spontaneous at low temperature but non-spontaneous at high temperature. Which of the following is true for the reaction?

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A reaction is spontaneous at low temperature but non-spontaneous at high temperature. Which of the following is true for the reaction?

(a) ΔH > 0, ΔS > 0

(b) ΔH < 0, ΔS > 0

(c) ΔH > 0, ΔS = 0

(d) ΔH < 0, ΔS < 0

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Correct answer: (d) ΔH < 0, ΔS < 0

Explanation: 

We know that ΔG = ΔH – TΔS

When ΔH < 0 and ΔS < 0 then ΔG will be negative at low temperatures (positive at high temperature) and the reaction will be spontaneous.

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