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A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 37.0ºC. As it does so, it absorbs 208 J of heat.

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A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 37.0ºC. As it does so, it absorbs 208 J of heat. The values of q and w for the process will be: (R = 8.314 J/mol K) (ln 7.5 = 2.01)

(a) q = + 208 J, w = – 208 J

(b) q = – 208 J, w = – 208 J

(c) q = – 208 J, w = + 208 J

(d) q = + 208 J, w = + 208 J

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Correct answer: (a) q = + 208 J, w = – 208 J

Explanation:

Process is isothermal reversible expansion, hence

ΔU = 0, therefore q = -w.

Since q = +208 J, W = -208 J

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