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Why is FeO(s) not formed in stoichiometric composition?
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12/09/2020 7:06 pm
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Why is FeO(s) not formed in stoichiometric composition?
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12/09/2020 7:09 pm
Iron oxide (FeO) has rock salt structure. In this case, O2 ions adopt on sites and Fe2+ ions should occupy non- stoichiometric.
This is the ideal arrangement. This oxide is always non-stoichiometric i.e., the composition of Fe2+ and O2 ions is not 1 : 1. It is 0.95 : 1 i.e. FeO95O(Wustite)
This composition can be obtained if a small number of Fe2+ ions are replaced by two-thirds of Fe3+
Eventually there would be less amount of metal as compared to stoichiometric composition.
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