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Differentiate between: (i) End-centred and face-centred unit cells. (ii) Monoclinic and hexagonal unit cells.

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Differentiate between:

(i) End-centred and face-centred unit cells.

(ii) Monoclinic and hexagonal unit cells.

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(i) End centred unit cell: 

  • They contain particles at the corners and one in the centre of any two opposite faces.
  • Total number of particles = 2

Face-centred unit cell:

  • They contain particles at the corners and one in the centre of each face.
  • Total number of particles = 4

(ii) Monoclinic unit cell:

a = b ≠ c

α = β = 90°

γ = 120°

Hexagonal unit cell

a ≠ b ≠ c

α = γ = 90°

Β ≠ 90°

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