Analysis shows that nickel oxide has the formula Ni0.98O1.00. What fractions of nickel exist as Ni^2+ and Ni^3+ ions?
Analysis shows that nickel oxide has the formula Ni0.98O1.00. What fractions of nickel exist as Ni2+ and Ni3+ ions?
The given formula of nickel oxide is Ni0.98O1.00
Thus, the ratio of the number of Ni atoms to the number of O atoms is,
Ni : O = 0.98 : 1.00 = 98 : 100
Now, Total charge on 100 O2- ions = 100 × (-2) = -200
Let the number of Ni2+ ions = x.
So, the number of Ni3+ ions is 98 - x.
Now, Total charge on Ni2+ ions = x(+2) = +2x
Similarly, total charge on Ni3+ ions = (98 - x)(+3) = 294 - 3x
As, the compound is neutral,
we can write: 2x + (294 - 3x) + (-200) = 0
⇒ −x + 94 = 0
⇒ x = 94
Therefore, number of Ni2+ ions = 94
And, number of Ni3+ ions = 98 − 94 = 4
Thus, the fraction of nickel that exists as Ni2+= 94/98 = 0.0959
And, the fraction of nickel that exists as Ni3+ = 4/98 = 0.041
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