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The alkali metals form salt-like hydrides by the direct synthesis at elevated temperature. The thermal stability of these hydrides decreases in which of the following orders?

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The alkali metals form salt-like hydrides by the direct synthesis at elevated temperature. The thermal stability of these hydrides decreases in which of the following orders?

(a) CsH > RbH > KH > NaH > LiH

(b) KH > NaH > LiH > CsH > RbH

(c) NaH > LiH > KH > RbH > CsH

(d) LiH > NaH > KH > RbH > CsH

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Correct answer: (d) LiH > NaH > KH > RbH > CsH

Explanation:

The stability of alkali metal hydrides decreases from Li to Cs. It is due to the fact that M–H bonds become weaker with increase in size of alkali metals as we move down the group from Li to Cs. Thus the order of stability of hydrides is

LiH > NaH > KH > RbH > CsH

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