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An unknown inorganic compound (X) loses its water of crystallization on heating and its aqueous solution gives the following reactions:

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An unknown inorganic compound (X) loses its water of crystallization on heating and its aqueous solution gives the following reactions:

(a) It gives a white turbidity with dilute HCl solution

(b) It decolourises a solution of iodine in potassium iodide

(c) It gives a white precipitate with silver nitrate solution which turns black on standing.

Identify the compound (X)

(a) Na2CO3.10H2O

(b) Na2S2O3.5H2O

(c) Na2SO4.10H2O

(d) None of these

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Correct answer: (b) It decolourises a solution of iodine in potassium iodide

Explanation:

X = Na2S2O3.5H2O

Na2S2O3 + 2HCl → 2NaCl + H2O + S + SO2

KI3 + 2Na2S2O3 → KI + 2NaI + Na2S4O6

2AgNO3 + Na2S2O3 → Ag2S2O3 + 2NaNO3

Ag2S2O3 + H2O → Ag2S + H2SO4

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