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Which of the following has the minimum heat of dissociation (a) (CH3)3N: → BF3 (b) (CH3)3N: → B(CH3)2F

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Which of the following has the minimum heat of dissociation

(a) (CH3)3N: → BF3

(b) (CH3)3N: → B(CH3)2F

(c) (CH3)3N: → B(CH3)3

(d) (CH3)3N: → B(CH3)F2

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Correct answer: (c) (CH3)3N: → B(CH3)3

Explanation:

Due to +I effect of methyl groups the Lewis character of B(CH3)3 decreases and coordination becomes weaker.

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