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The correct order of increasing C – O bond length of CO, CO2 and CO3^2- is

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The correct order of increasing C – O bond length of CO, CO2 and CO32- is

(a) CO32- < CO2 < CO

(b) CO2 < CO32- < CO

(c) CO < CO32- < CO2

(d) CO < CO2 < CO32-

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Correct answer: (d) CO < CO2 < CO32-

Explanation:

Structures of CO, CO2 and CO32- are

C = O  O = C = O

Compound - CO - CO2 - CO3

Bond order - 3  -  2 -  1.33

Bond order ∝ \(\frac{1}{Bond\;length}\)

Hence, the decreasing (C - O) bond length is CO < CO2 < CO32-

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