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B(OH)3 + NaOH → NaBO2 + Na[B(OH)4] + H2O How can this reaction is made to proceed in forward direction?

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B(OH)3 + NaOH → NaBO2 + Na[B(OH)4] + H2O

How can this reaction is made to proceed in forward direction?

(a) addition of cis 1, 2-diol

(b) addition of borax

(c) addition of trans 1, 2-diol

(d) addition of Na2HPO4

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Correct answer: (a) addition of cis 1, 2-diol

Explanation:

H3BO3 acts as weak monobasic Lewis acid.

B(OH)3 + NaOH → Na[B(OH)4]

On addition of cis-1, 2-diol in H3BO3 solution, acidic strength of H3BO3 increases due to chelation effect.

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