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Critical temperatures for A, B, C and D gases are 25°C, 10°C, –80°C and 15°C respectively. Which gas will be liquefied more easily?

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Critical temperatures for A, B, C and D gases are 25°C, 10°C, –80°C and 15°C respectively. Which gas will be liquefied more easily?

(a) A

(b) B

(c) C

(d) D

1 Answer
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(a) A

Explanation:

Critical temperature of a gas is given by

TC = 8a/27Rb => a ∝TC

where a is measure of vander Waal's forces of attraction. Higher the critical temperature of a gas greater the intermolecular forces of attraction between the molecules of gas and easily the gas can be liquefied. Hence gas A whose critical temperature (25°C) is highest among all the given options will be liquified more easily.

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