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Equal masses of methane and oxygen are mixed in an empty container at 25°C. The fraction of the total pressure exerted by oxygen is

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Equal masses of methane and oxygen are mixed in an empty container at 25°C. The fraction of the total pressure exerted by oxygen is

(a) \(\frac{1}{2}\)

(b) \(\frac{2}{3}\)

(c) \(\frac{1}{3}\) x \(\frac{273}{298}\)

(d) \(\frac{1}{3}\)

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Correct answer: \(\frac{1}{3}\)

Explanation:

Let the mass of methane and oxygen = m gm.

Mole fraction of O2

= \(\frac{Moles\;of\;O_2}{Moles \; of\;O_2 + Moles\;of\;CH_4}\)

= \(\frac{\frac{m}{32}}{\frac{m}{32}+ \frac{m}{16}}\)

= \(\frac{\frac{m}{32}}{\frac{3m}{32}}\)

= \(\frac{1}{3}\)

Partial pressure of O2 =

Total pressure × mole fraction of O2,

PO2 = P x \(\frac{1}{3}\) = \(\frac{1}{3}\)P

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