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What is the decreasing order of strength of the bases OH^-, NH2^-, HC ≡ C^- and CH3CH2^-?
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22/01/2022 2:34 pm
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What is the decreasing order of strength of the bases OH-, NH2-, HC ≡ C- and CH3CH2-?
(a) CH3CH2- > NH2- > HC ≡ C- > OH-
(b) HC ≡ C-> CH3CH2-> NH2- > OH-
(c) OH- >NH2- > HC ≡ C- > CH3CH2-
(d) NH2- > HC ≡ C- > OH- > CH3CH2-
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22/01/2022 2:37 pm
Correct answer: (a) CH3CH2- > NH2- > HC ≡ C- > OH-
Explanation:
Stronger the acid, weaker the conjugate base. Since acid character follows the order
H2O > HC ≡ CH > NH3 > CH3 - CH3
(Acid character), the basic character of their conjugate bases decreases in the reverse order, i.e.,
CH3CH2- > NH2- > HC ≡ C- > OH-
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