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What is the decreasing order of strength of the bases OH^-, NH2^-, HC ≡ C^- and CH3CH2^-?

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What is the decreasing order of strength of the bases OH-, NH2-, HC ≡ C- and CH3CH2-?

(a) CH3CH2- > NH2- > HC ≡ C- > OH-

(b) HC ≡ C-> CH3CH2-> NH2- > OH-

(c) OH- >NH2- > HC ≡ C- > CH3CH2-

(d) NH2- > HC ≡ C- > OH- > CH3CH2-

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Correct answer: (a) CH3CH2> NH2> HC ≡ C> OH-

Explanation:

Stronger the acid, weaker the conjugate base. Since acid character follows the order

H2O > HC ≡ CH > NH3 > CH3 - CH3

(Acid character), the basic character of their conjugate bases decreases in the reverse order, i.e.,

CH3CH2> NH2> HC ≡ C> OH-

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