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The impure 6 g of NaCl is dissolved in water and then treated with excess of silver nitrate solution. The mass of precipitate of silver chloride is found to be 14 g.

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The impure 6 g of NaCl is dissolved in water and then treated with excess of silver nitrate solution. The mass of precipitate of silver chloride is found to be 14 g. The % purity of NaCl solution would be:

(a) 95%

(b) 85%

(c) 75%

(d) 65%

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Correct answer: (a) 95%

Explanation:

The reaction that takes place is

NaCl + AgNO3 → AgCl↓ + NaNO3

∴ 143.5 g of AgCl is produced from 58.5 g NaCl

∴ 14 g of AgCl will be produced from

\(\frac{58.5 \times 14}{143.5}\) = 5.70g NaCl

This is the amount of NaCl in common salt;

% purity = \(\frac{5.70}{6}\)x 100 = 95%

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