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1.575 g of oxalic acid (COOH)2.xH2O are dissolved in water and the volume made upto 250 mL. On titration 16.68 mL of this solution requires 25 mL of N/15 NaOH solution for complete neutralization, calculate x.

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1.575 g of oxalic acid (COOH)2.xH2O are dissolved in water and the volume made upto 250 mL. On titration 16.68 mL of this solution requires 25 mL of N/15 NaOH solution for complete neutralization, calculate x.

(a) 3

(b) 2

(c) 4

(d) 5

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Correct answer: (b) 2

Explanation:

Meq of oxalic acid in 16.68 ml = Meq of NaOH

= 25 x \(\frac{1}{15}\)

Meq of oxalic acid in 250 ml

= 25 x \(\frac{1}{15}\) x \(\frac{250}{16.68}\) = 24.98

\(\frac{1.575}{\frac{(90 + 18x)}{2}}\) x 1000 = 24.98

∴ x = 2

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