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Which of the following 0.10 m aqueous solutions will have the lowest freezing point?

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Which of the following 0.10 m aqueous solutions will have the lowest freezing point?

(a) Al2(SO4)3

(b) C6H12O6

(c) KCl

(d) C12H22O11

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(a) Al2(SO4)3

Explanation:

Depression in freezing point ∝ No. of particles.

(when concentration of different solutions is equal)

Al2(SO4)3 provides five ions on ionisation

Al2(SO4)→ 2Al3+ + 3SO2-4

while KCl provides two ions

KCl 3/4 → K+ + Cl-

C6H12O6 and C12H22O11 are not ionised

so they have single particle in solution.

Hence, Al2(SO4)3 have maximum value of depression in freezing point or lowest freezing point.

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