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[Solved] Exactly 1 g of urea dissolved in 75 g of water gives a solution that boils at 100.114°C at 760 torr.

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Exactly 1 g of urea dissolved in 75 g of water gives a solution that boils at 100.114°C at 760 torr. The molecular weight of urea is 60.1. The boiling point elevation constant for water is

(a) 1.02

(b) 0.51

(c) 3.06

(d) 1.51

1 Answer
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(b) 0.51

Explanation:

Weight of solute (w) = 1 g

Weight of solvent (W) = 75 g

Boiling point of solution = 100.114°C

Boiling point of solvent = 100°C

ΔT = 100.114 – 100 = 0.114°C

Molecular weight of solute (m) = 60.1

Boiling point elevation constant (K) = ?

m = (1000 x K x w)/ΔT x W

K = (m x ΔT x W)/ 100 x w

= (60.1 x 0.114 x 75)/1000 x 1

= 513.8/1000 = 0.513

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