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Which of the following arrangements represents the increasing order (smallest to largest) of ionic radii of the given species O^2–, S^2–, N^3–, P^3–?

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Which of the following arrangements represents the increasing order (smallest to largest) of ionic radii of the given species O2–, S2–, N3–, P3–?

(a) O2– < N3– < S2– < P3–

(b) O2–< P3– < N3– < S2–

(c) N3– < O2– < P3– < S2–

(d) N3– < S2– < O2– < P3–

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Correct answer: (a) O2– < N3– < S2– < P3–

Explanation:

For isoelectronic species ionic radii decreases as the charge on ion decreases. Further on moving down in a group ionic radii increases. Hence the correct order is O2– < N3– < S2– < P3–

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