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The species that has a spin-only magnetic moment of 5.9 BM, is :

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The species that has a spin-only magnetic moment of 5.9 BM, is : (Td = tetrahedral)

(1) Ni(CO)4 (Td)

(2) [Ni(CN)4]2- (square planar)

(3) [NiCl4]2- (Td)

(4) [MnBr4]2- (Td)

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(4) [MnBr4]2- (Td)

Explanation:

(1) Ni(CO)4 - 3d10 - 0

(2) [Ni(CN)4]2- 3d8  0

(3) [NiCl4]2- 3d8  0

(4) [MnBr4]2- 3d5  0

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