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Number of compounds which have greater freezing point than 0.1 M ethanol (Assume molarity = molality)

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Number of compounds which have greater freezing point than 0.1 M ethanol (Assume molarity = molality)

(a) 0.1 M Na2SO4

(b) 0.1 M Ba3(PO4)2

(c) 0.1 M HCl

(d) 0.1 M NaOH

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∆Tf = i Kf m

Since all solutions have the same concentration, ∆Tf will depend only on i.

i values are as follows:

Ethanol = 1

Na2SO4 = 3

Ba3(PO4)2 = 5

HCl = 2

NaOH = 2

Thus, all the given solutions will have more depression in freezing point than ethanol, i.e., they will have lesser freezing point than 0.1 M ethanol.

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