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Consider the following reactions A → P1 ; B → P2 ; C → P3 ; D → P4, The order of the above reactions are a, b, c and d, respectively.

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Consider the following reactions

A → P1 ; B → P2 ; C → P3 ; D → P4,

The order of the above reactions are a, b, c and d, respectively. The following graph is obtained when log[rate] vs.log[conc.] are plotted :

Among the following, the correct sequence for the order of the reactions is :

(1) d > b > a > c

(2) a > b > c > d

(3) c > a > b > d

(4) d > a > b > c

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(1) d > b > a > c

Explanation:

Rate = K[Conc]order

logRate = log K + order log[conc]

so slope of graph is order of reaction.

greater the slope greater is order of reaction

so order of reaction => “A < B < C < D”

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