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Which of the following is a natural polymer?

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Which of the following is a natural polymer?

(1) poly (Butadiene-styrene)

(2) polybutadiene

(3) poly (Butadiene-acrylonitrile)

(4) cis-1, 4-polyisoprene

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Correct answer:  (4) cis-1, 4-polyisoprene

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