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Which one of the following molecules is paramagnetic?

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Which one of the following molecules is paramagnetic?

(a) N2

(b) NO

(c) CO

(d) O3

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Correct answer: (b) NO

Explanation:

The molecular orbital configuration of the molecules given is

Total no. of electrons in NO = 7(N) + 8(O) = 15

Hence E.C. of NO

= KKσ(2s)2σ*(2s)2 σ(2pz)2

π(2px)2 = π(2py)2π*(2px)1 = π*(2py)o

Due to presence of one unpaired electron NO is paramagnetic.

Except NO all are diamagnetic due to absence of unpaired electrons.

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