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The formation of molecular complex BF3 – NH3 results in a change in hybridization of boron

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The formation of molecular complex BF3 – NH3 results in a change in hybridization of boron

(a) from sp2 to dsp2

(b) from sp2 to sp3

(c) from sp3 to sp2

(d) from sp3 to sp3d

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Correct answer: (b) from sp2 to sp3

Explanation:

In BF3, B is sp2 hybridized with one empty pz orbital. The empty pz orbital of BF3 can be filled by lone pair of molecules such as NH3. When this occurs a tetrahedral molecule or ion is formed which is sp3 hybridized.

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