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Molecular AB has a bond length of 1.61Å and a dipole moment of 0.38 D. The fractional charge on each atom (absolute magnitude) is

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Molecular AB has a bond length of 1.61Å and a dipole moment of 0.38 D. The fractional charge on each atom (absolute magnitude) is (e0 = 4.802 × 10–10 esu)

(a) 0.5

(b) 0.05

(c) 0

(d) 1.0

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Correct answer: (b) 0.05

Explanation:

1 e = 1.602 × 10–19C

1 esu = 3.33 × 10–10C

\(\frac{1e}{1esu}\) = \(\frac{1.602 \times 10^{-19}C}{3.33 \times 10^{-10}C}\)

1 e = 4.802 × 10–10 esu

Dipole moment = q × distance

⇒ 1 D ≈ 10–18 esu cm

0.38 × 10–18 esu cm = q × (1.61 × 10–8 cm)

q = 2.36 × 10–11 esu

q = \(\frac{2.36 \times 10^{11}esu}{4.802\times 10^{10}esu}\)

q = 0.049

q ≈ 0.05 fractional charge

This post was modified 3 years ago 2 times by Shivani siva
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