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[Solved] CaO and NaCl have the same crystal structure and approximately the same ionic radii. If U is the lattice energy of NaCl, the approximate lattice energy of CaO is

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CaO and NaCl have the same crystal structure and approximately the same ionic radii. If U is the lattice energy of NaCl, the approximate lattice energy of CaO is

(a) U/2

(b) U

(c) 4C

(d) 2U

1 Answer
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(c) 4C

Explanation:

Lattice energy = \(\frac{Product\;of\;charges}{interionic\;distance}\)

In NaCl the product of charges = 1 × 1;

In CaO product of charges = 2 × 2 = 4 while the interionic distance is almost same in both.

Thus lattice energy of CaO is almost four times the lattice energy of NaCl.

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