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What is the role of metal or reagents written on arrows in the given chemical reactions?

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What is the role of metal or reagents written on arrows in the given chemical reactions?

(b) CH3COOH + CH3CH2OH + Conc.H2SO4 → CH3COOC2H5 + H2O

(c) CH3CH2OH + Alk. KMnO4 + Heat →  CH3COOH

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(a) Ni is used as a catalyst.

(b) Cone. H2SO4 acts as a dehydrating agent.

(c) Alkaline KMnO4 is an oxidising agent.

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