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Which one of the following is linked to the discovery of Bordeaux mixture as a popular fungicide?

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Which one of the following is linked to the discovery of Bordeaux mixture as a popular fungicide?

(1) Loose smut of wheat

(2) Bacterial leaf blight of rice

(3) Black rust of wheat

(4) Downy mildew of grapes

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(4) Downy mildew of grapes

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